The tires on my truck usually run at 35 psi, unless I'm going loaded to a show. Then I run them up to 40 on the back and 38 on the front. Your truck being a 2500 series, it's probably got LT series light truck tires that are 10 ply and run around 75 psi. It should have a specified amount in the owner's manual handbook for the size tire and load range. When I get done with work I will look at my manual and post it.
Mine are currently around 75psi rear and 50psi front which is specified in the door jamb sticker - along with another sticker that says they can run a lot lower. I'll check the figures later.
They are too high as they are and are transmitting a lot of noise. As I leave the house here, the tarmac is worn through to the 'washboard' surface grading that was done during its last re-tar. It's horrible!