Engine heat (combined with exposure to the elements) is what caused that hardware to seize to begin with. Warming-up the engine is pointless.
You wanna use heat, get an Oxy-Acetylene torch. That allows you to add tremendous, LOCALIZED heat, so that you can use differential expansion to your advantage. The point is to heat one item fast enough that the heat doesn't have time to transfer to the other item. Heat the piss out of the manifold flange where each stud is, one at a time. Remove each stud while the manifold is still glowing. The studs should be considered disposable. OTOH, if you're replacing the manifolds with headers, there's no reason not to just break the studs, you're not reusing 'em. You could try heating the bolt heads at the cylinder head end of the manifold; but I don't think you can expect miracles with them. You'll never get the bolts hot, deep enough to do any good. At any rate, heat the heads, then let 'em cool before removing.
Yeah, exhaust work often SUCKS. As I said, you need to go into the job with the attitude that it's all getting scrapped. Whatever you can salvage is bonus.