I will say this, ARP stainless steel is not the same kind of stainless as your 316 grade stuff from the hardware store. It's significantly harder. If I had iron heads, I think I'd like to try them.
I've used stainless ARP bolts in quite a few other applications, but I have not personally used them in a header application yet. I have used general-duty stainless bolts many times on collectors (both ball and socket/3-bolt flanged) without issue. Most of my vehicles with headers have aluminum heads, I was afraid to try stainless in those applications. One vehicle with iron heads I had studs with a few bolts where there wasn't clearance. They were inevitably rusty, too.
I vouch try them and let us know how it goes!